Tris (dibenzylideneacetone) dipalladium (0) Cas: 51364-51-3 Awọn kirisita eleyi ti
Nọmba katalogi | XD90729 |
Orukọ ọja | Tris (dibenzylideneacetone) dipalladium (0) |
CAS | 51364-51-3 |
Ilana molikula | C51H42O3Pd2 |
Òṣuwọn Molikula | 915.71738 |
Awọn alaye ipamọ | 2 si 8 °C |
Ti irẹpọ Owo idiyele koodu | 28439000 |
Ọja Specification
Ifarahan | Awọn kirisita eleyi ti |
Ayẹwo | 99% |
Ojuami yo | 152-155 ℃ |
Oju omi farabale | ° ologbo760mmHg |
PSA | 51.21000 |
logP | 11.94690 |
Tris (dibenzylideneacetone) dipalladium (0) jẹ ayase palladium odo-valent pataki, eyiti o jẹ lilo pupọ ni awọn aati bii sisopọ, hydrogenation, ati carbonylation ni iṣelọpọ Organic.Ti a lo ni apapo pẹlu awọn ligands oriṣiriṣi, o jẹ fọọmu ni ipo ohun elo ti nṣiṣe lọwọ odo-valent palladium ti o lagbara pupọ, eyiti o jẹ lilo pupọ ni mnu erogba-erogba ati awọn aati idasile didi carbon-heteroatom.
Gẹgẹbi ayase, o ti lo ni awọn aati idapọ ti Suzuki, Kumada, Negishi, Buchwald, ati bẹbẹ lọ Tris (dibenzylideneacetone) dipalladium ti wa ni lilo lati ṣeto awọn polymers semiconducting, eyiti a ṣe ilana lati awọn nkan ti ko ni chlorinated sinu awọn transistors tinrin fiimu ti o ga julọ.Tun lo ninu iṣelọpọ ti polima olopobobo heterojunction oorun ẹyin bi semikondokito.
Aryl kiloraidi Suzuki oluṣeto ifasilẹ idapọmọra;Aryl kiloraidi hekki ayase lenu isepo;ayase lenu arylation ketone;Aryl halide Buchwald-Hartwig amination lenu ayase;Alyl kiloraidi fluorination ayase lenu;Carboxyl Catalysts fun β-arylation ti esters;awọn olutọpa fun carbonylation ti 1,1-dichloro-1-alkenes;awọn oluranlọwọ fun iyipada ti aryl ati awọn triflates fainali si aryl ati awọn halides fainali.