Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate Cas: 99604-67-8 Iyẹfun osan ofeefee
| Nọmba katalogi | XD90827 |
| Orukọ ọja | Pentamethylcyclopentadienyltris (acetonitrile) ruthenium (II) hexafluorophosphate |
| CAS | 99604-67-8 |
| Ilana molikula | C16H24F6N3PRu |
| Òṣuwọn Molikula | 504.42 |
| Awọn alaye ipamọ | 2-8°C |
Ọja Specification
| Ifarahan | Yellow Orange Powder |
| Ayẹwo | 99% |
Awọn eka [Cp * Ru(MeCN) 3] PF6 ṣe afihan lati ṣe itusilẹ hydrosilylation ti ọpọlọpọ awọn alkynes.Alkynes ebute ni iraye si awọn ọja alpha-vinylsilane pẹlu regioselectivity to dara.Awọn ijinlẹ isamisi Deuterium tọkasi ilana afikun trans ti o mọ wa ni iṣẹ.eka kanna naa n ṣiṣẹ ni alkyne hydrosilylation ti inu, nibiti a ti ṣetọju yiyan yiyan pipe fun ilana afikun trans.Orisirisi awọn kilasi sobusitireti alkyne inu, pẹlu awọn ọti-lile propargylic ati alpha, awọn agbo ogun beta-alkynyl carbonyl, gba didasilẹ vinylsilane regioselective.Ifarada ti ọpọlọpọ awọn silanes jẹ akiyesi, pẹlu alkyl-, aryl-, alkoxy-, ati halosilanes.Anfani yii jẹ afihan ni iṣelọpọ taara ti awọn sobusitireti triene fun silikoni-tethered intramolecular Diels-Alder cycloadditions.
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